Product ID:AUTOCOAT LV MM TONER 444 005444
MSDS Date:04/27/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLJXZ

AKZO NOBEL COATINGS INC.

5555 SPALDING DRIVE
NORCROSS, GA 30092
US

Emergency Phone: (800) 424-9300

Info Phone: 770-441-8628 USA(7AM-4PM EAST TIME)

Preparer: AKZO CAR REFINISH MFG DPT

Cage: AKZNB

AKZO NOBEL COATINGS LTD.

ETOBICOKE, ONTARIO, M9W5S6, ON 30092 CN

Telephone: UNK

Cage: TO942

ETHYL AMYL KETONE. (MFR CAS# 541-85-5) (VAPOR PRESSURE

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

2.1, LD50 (ORAL, RAT)

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

N.AP., LD50 (ORAL,

CAS: 471-34-1

RTECS: FF9335000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

N.AP., LD50 (ORAL, RAT)

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 0.003%

OSHA PEL .05 MG/M3

ACGIH TLV: 0.05 MG/M3

N.AP., LD50 (ORAL, RAT)

CAS: 112926-00-8

RTECS: VV7315000

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

N.AP., LD50 (ORAL,

CAS: 9002-88-4

RTECS: KX3270000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

N.AP., LD50

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CANCER HAZARD. CONTAINS CRYSTALLINE
SILICA WHICH IS LISTED AS A LUNG CARCINOGEN . PRIMARY ROUTES OF
ENTRY: INHALATION, SKIN CONTACT, INGESTION, EYES. ACUTE:
INHALATION: NASAL & RESP IRRIT, NAUSE A, COUGH, DIZZINESS,
WEAKNESS, HEADACHE, DROWSINESS, FATIGUE, CHEST PAIN, VOMITING, CNS
EFFECTS, ASPHYXIATION, LACK OF COORDINATION. SKIN CONTACT:
EXTRACTION OF NATURAL OILS WITH RESULTING DRY SKIN, I RRIT, REDNESS
& DERMATITIS. CAN BE ABSORBED THROUGH THE SKIN INTO THE BLOOD. EYE
CONTACT: IRRIT, REDNESS, PAIN, BLURRED VISION, SENSATION OF SEEING
HALOS AROUND LIGHTS & REVERSIBLE DAMAGE. INGESTION: GI IRRITATION,
(OVEREXPOSURE)
Explanation of Carcinogenicity:QUARTZ CRYSTALLINE SILICA: IARC GROUP 1,
VOLUME 68, PAGE 41, 1997; NTP NINTH ANNUAL REPORT, KNOWN TO BE
HUMAN CARCINOGENS LIST.
Effects of Overexposure:HEALTH HAZ (CONT): NAUSEA, VOMIT, DIARRHEA,
DROWSY, LACK OF COORDINATION, CNS EFFECTS, DEPRESSION. CHRONIC:
REPEATED OVEREXPOSURE MAY CAUSE CNS DAMAGE, LUNG & KIDNEY DAMAGE,
LIVER ABNORMALITIES, REPR ODUCTIVE ORGAN DAMAGE, BLOOD EFFECTS,
DERMATITIS. OTHER HEALTH EFFECTS: INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE
HARMFUL/FATAL. REPORTS HAVE ASSOC REPEATED & PROLONG ED
OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS
SYSTEM DAMAGE. SIGNS OF OVEREXPOS: NAUSEA, COUGH, DIZZY, WEAKNESS,
HEADACHE, CHEST PAIN, LACK OF COORDINATION, SHORTNESS OF BREATH,
DERMATITIS, REDNESS &/OR PAIN IN EYES.
Medical Cond Aggravated by Exposure:SKIN DISORDERS, LIVER CONDITIONS,
KIDNEY CONDITIONS, NEUROLOGICAL DISORDERS, PREGNANCY, REPRODUCTIVE
SYSTEM DISORDERS.

First Aid:IN ALL CASES IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
INHALATION: MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING, WASH WITH
SOAP AND WATER OR RECOGNIZED CLEANER. DO NOT USE SOLVENTS OR
THINNERS. EYE CONTACT: CONTACT LENSES MUST BE REMOVED, FLUSH WITH
WATER FOR AT LEAST 15 MINUTES, CONSULT A PHYSICIAN IMMEDIATELY.
INGESTION: DRINK ONE OR TWO GLASSES OF WATER TO DILUTE. DO NOT
INDUCE VOMITING. CONSULT A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY. TREAT SYMPTOMATICALLY.

Flash Point Method:SCC
Flash Point:=26.7C, 80.F
80-92F (27-33C).
Lower Limits:0.9
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG OR
SPRAY. WATER JET OR STREAM IS UNSUITABLE. NFPA 704: HEALTH-2,
FLAMMABILITY-2, REACTIVITY-0.
Fire Fighting Procedures:WATER SHOULD BE USED TO COOL CONTAINERS
EXPOSED TO FIRE. FIRE FIGHTING PERSONNEL SHOULD WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT .
NFPA FLAMMABILITY/C LASS: 1C. FLAMMABLE LIQUID, REFER TO GUIDE 127
OF THE NORTH AMERICAN EMERGENCY GUIDE BOOK. PRODUCT USE: COLOR
COAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. FIRE WILL PRODUCE DENSE BLACK SMOKE
CONTAINING HAZARDOUS PRODUCTS OF COMBUSTION. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT. OBTAIN MEDICAL AT TN. FORMS EXPLOSIVE MIXTURE
WITH AIR. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO A SOURCE OF
IGNITION AND FLASH BACK.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS, VENTILATE CONFINED AREA. DIKE TO REDUCE EXTENT OF
SPILL. REMOVE WITH INERT ABSORBENT (VERMICULITE, CLAY, OIL-DRY,
KITTY LITTER, ETC.) USING NON- SPARKING TOOLS. TRANSFER TO GROUNDED
METAL CONTAINER, SEAL CONTAINER. DISPOSE OF AS HAZARDOUS WASTE. IF
NECESSARY REPORT TO APPLICABLE GOVERNMENT AGENCY.

Handling and Storage Precautions:USE APPROVED BONDING & GROUNDING
PROCEDURES WHEN TRANSFERRING LIQUID TO ANOTHER CONTAINER. DO NOT
TRANSFER TO UNLABELED CONTAINERS. NO SMOKING. STORE IN PLASTIC
CNTNRS OF FLAMMABLE LIQUIDS INSIDE CLOS ED APPROVED BOXES OR SAFETY
CABINETS. STORE CNTNRS OUT OF SUN, AWAY FROM HEAT, SPARKS & (OTHER
PREC)
Other Precautions:HNDLG/STOR (CONT): OPEN FLAMES. CLOSE ALL CONTAINERS
AFTER EACH USE. CONSULT NFPA & LOCAL CODES FOR MORE STORAGE
REQUIREMENTS. VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG FLOOR.
USE EXPLOSION PROOF EQUIP IN AREA WHERE THERE IS SPRAYING/OPEN
CONTAINERS. DO NOT TAKE INTERNALLY. OBSERVE LABEL PRECAU TIONS.
(OTHER INFO)

Respiratory Protection:WHEN PERSONNEL, WHETHER SPRAYING OR NOT, ARE
INSIDE SPRAY BOOTH, VENTILATION IS UNLIKELY TO BE SUFFICIENT TO
CONTROL PARTICULATES & CHEM VAPOR IN ALL CASES. IN SUCH CASES NIOSH
APROVED AIR SUPPLIED RE SP EQUIPMENT RECOMMENDED UNTIL PARTICULATE
& VAPOR CONC HAS FALLEN BELOW EXPOSURE LIMITS. IF MONITORING
DEMONSTRATES LEVEL BELOW TLV/PEL WEAR (OTHER PROT EQUIP)
Ventilation:PROVIDE SUFFICIENT VENTILATION TO KEEP VAPOR CONCENTRATIONS
BELOW GIVEN TLV &/OR PEL. FOR BAKING FINISHES, EXHAUST VAPORS
EMITTED DURING HEATING. (SUPP SAFETY)
Protective Gloves:REQ'D FOR PROLONGED REPEATED CONTACT. USE SOLVENT
RESISTANT GLOVES.(STATE REGS)
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD .
Other Protective Equipment:ANTI STATIC PAINT SUIT. EYEWASH AND DELUGE
SHOWER MEETING ANSI DESIGN CRITERIA . RESP PROT (CONT): NIOSH
APPROVED RESPIRATOR DEVICE. SEE SAFETY EQUIP SUPPLIER FOR
RECOMMENDATION & (HYGIENE PRAC)
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING THE
WASHROOM. LAUNDER CLOTHING BEFORE REUSE. OTHER PROT EQUIP (CONT):
EVALUATION. WEAR ORGANIC VAPOR CARTRIDGE RESPIRATOR WHEN HANDLING.
Supplemental Safety and Health
VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG FLOORS. MATERIAL HAS
OFFENSIVE ODOR. PROLONGED EXPOS MAY REDUCE THE USER'S SENSITIVITY
TO THE ODOR, THUS REDUCING EFFECTIVENESS OF ODOR AS A WARNING AGA
INST EXPOSURE. VENTILATION (CONT): REMOVE DECOMP PROD FORMED DURING
WELDING/FLAME CUTTING OF SURFACES COATED W/PROD.

Boiling Pt:=93.3C, 200.F
B.P. Text:200-380F (93-193C)
Vapor Density:> AIR.
Spec Gravity:0.97 - 1.54.
VOC Grams/Liter:3.
Evaporation Rate & Reference:SLOWER THAN ETHER.
Appearance and Odor:COLORED LIQUID. ORGANIC ODOR.
Percent Volatiles by Volume:40 - 42.5

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ALKALI METALS, HYDROGEN FLUORIDE, NITRIC ACID, SODIUM
HYDROXIDE.
Stability Condition to Avoid:HEAT, OPEN FLAMES, SPARKS. WASTE
DISPOSAL (CONT): WHEN DISCARDED IN ITS SUPPLIED FORM, PRODUCT MEETS
HAZARD CRITERIA OF 'IGNITABILITY' & MUST BE CONSIDERED AS HAZARDOUS
WASTE D001.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN, VARIOUS
HYDROCARBONS, TOXIC FUMES.

Waste Disposal Methods:DISPOSE OF IAW FEDERAL, STATE, PROVINICIAL &
LOCAL POLLUTION REQUIREMENTS. IN ADDITION, RAGS, SPRAY BOOTH
FILTERS, PAINT SUITS, EMPTY CANS, ETC., CONTAMINATED WITH PRODUCT
MAY BE HAZARDOUS WASTE. DETE RMINE WHETHER CONTAMINATED ITEMS ARE
HAZARDOUS & DISPOSE OF AS APPROPRIATE. CLEAN PREFERABLY W/DETER
GENT, AVOID USING SOLVENTS. (CONDITIONS TO AVOID)

Toxicological Information:SENSITIZATION: PRODUCT MAY CAUSE SKIN & INHAL
SENSITIZATION TO CERTAIN INDIVIDUALS. TERATOGENICITY: NONE KNOWN.
REPRODUCTIVE TOXICITY: NONE KNOWN. TLV: NONE ESTAB FOR THIS PROD.
CARCINOGENICITY: ALL PRODUCTS: PRODUCT CONTAINS ETHYLBENZENE. A
DRAFT REPORT ON STUDY CONDUCTED BY NTP STATES THAT LIFETIME
INHALATION EXPOS OF RATS & MICE TO CONC OF ETHYLBENZENE (750 PPM)
RESULTED IN INCREASES IN CERTA IN TYPES OF CANCER, INCLUDING KIDNEY
TUMORS IN RATS & LUNG & LIVER IN MICE. EFFECTS WERE NOT OBSERVED
IN ANIMALS EXPOSED TO LOWER CONC OF ETHYLBENZENE (75 PPM OR 250
PPM). THE DRAFT REPORT DOES NOT A DDRESS RELEVANCE OF RESULTS TO
HUMANS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:GENERAL INFORMATION: AVOID RUNOFF INTO GROUND, STORMS OR
SEWERS WHICH LEAD INTO WATERWAYS. WATER RUNOFF CAN CAUSE
ENVIRONMENTAL DAMAGE. ENVIRONMENTAL IMPACT DATA (PERCENTAGE BY
WEIGHT): VOC: SEE PHYSI CAL/CHEMICAL. OZONE DEPLETORS: NONE. HEAVY
METALS: NONE. US FEDERAL HAZARDOUS AIR POLLUTANTS: XYLENE, NICKEL,
TOLUENE, ETHYLBENZENE. SEE INDIVIDUAL COMPOSITIONS. THERE ARE
EXTENSIVE ECOLOGICAL DATA AV AILABLE ON THE VARIOUS COMPONENTS OF
THIS PRODUCT. AN ADEQUATE REPRESENTATION OF ALL THESE DATA IS
BEYOND THE SCOPE OF THIS DOCUMENT. PLEASE CONTACT THE INFORMATION
PHONE NUMBER.

Transport Information:GROUND SHIPMENTS: FOR INNER CONTAINERS OF 5L OR
LESS USE ONLY PROPER AKZO NOBEL OR UN SPECIFIED OUTER CONTAINERS.
POSITIVELY CLOSE ALL SEAMS. SHIPPER MUST BE TRAINED & CERTIFIED TO
HANDLE HAZARDOUS MA TERIALS IN GROUND TRANSPORTATION (DOT/TDG). FOR
CONTAINERS GREATER THAN 5L USE 1A1 CONTAINERS. PROPER SHIPPING
NAME: PAINT. HAZARD CLASS OR DIVISION: 3. UN IDENTIFICATION #:
UN1263. PACKAGING GROUP: I II. HAZARD LABEL: FLAMMABLE LIQUID.
OCEAN SHIPMENTS: FOR INNER CONTAINERS OF 5L OR LESS USE ONLY AKZO
NOBEL OR UN SPECIFICATION CONTAINERS. POSITIVELY CLOSE ALL SEAMS.
FOR CONTAINERS OF OVER 5L USE 1A 1 CONTAINERS. SHIPPER MUST BE
(SARA)

SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
NONE. SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE HEALTH, DELAYED
HEALTH, FIRE HAZARD: NONE LISTED. TRANSPORT (CONT): MUST BE TRAINED
& CERTIFIED TO HANDLE HAZARDOUS MATERIALS IN MARINE TRANSPORTATION
(IMO/IMDG). PROPER SHIPPING NAME: PAINT. UN ID #: UN1263. PACKAGING
GROUP: III. HAZARD LABEL: FLAMMABLE LIQUID. HAZARD CLASS OR
DIVISION: 3.3. IMDG PAGE ( ENGLISH TRANSLATION): 3372. MARINE
POLLUTANT: NO. AIR SHIPMENTS: PRODUCTS OF 5L OR LESS MUST BE
REPACKAGED FOR AIR TRANSPORTATION (FED REG)
Federal Regulatory Information:OSHA: THIS PRODUCT IS CONSIDERED
HAZARDOUS UNDER THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD.
WHMIS: B2:D1A; D2A. TSCA STATUS: ALL INGREDIENTS ARE TSCA
REGISTERED. CEPA STATUS: ONE INGREDIENT IS NO T LISTED ON THE DSL
OR NDSL. FED REGS (CONT): INTO UN SPECIFICATION OUTER PACKAGINGS
DESIGNED FOR TRANSPORTATION BY AIR. THE SHIPPER MUST BE TRAINED AND
CERTIFIED TO SHIP HAZARDOUS MATERIALS IN AIR TR ANSPORTATION
(ICAO/IATA). PROPER SHIPPING NAME: PAINT. HAZARD CLASS OR DIVISION:
3. UN ID#: UN1263. PACKAGING GROUP: III. HAZARD LABEL: FLAMMABLE
LIQUID. PACKAGING INSTRUCTIONS PASSENGER AIRCRAFT (IATA ENGLISH
TRANSLATION): (STATE REG)
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER: QUARTZ CRYSTALLINE SILICA. FEDERAL REGULATIONS
(CONT): 309 OR Y309. PACKAGING IN STRUCTIONS CARGO AIRCRAFT (IATA
ENGLISH TRANSLATION): 310. SPECIAL PROVISIONS: A3, A7, A72.